Gas hydrate prevention technology in low-temperature conditioning using ultra-high frequency radiation energy
T. Podoliak1, https://orcid.org/0009-0008-5287-0880
V. Dmytrenko1 https://orcid.org/0000-0002-1678-2575
1National University «Yuri Kondratyuk Poltava Polytechnic», Poltava, Ukraine
Coll.res.pap.nat.min.univ. 2026, 84:134–148
Full text (PDF)
https://doi.org/10.33271/crpnmu/84.134
ABSTRACT
Purpose. Improving the efficiency of methanol use in low-temperature gas treatment processes under hydrate formation conditions by utilizing ultra-high frequency radiation energy.
The methods. The analysis of hydrocarbon was carried out using physical, chemical and physicochemical research methods. The study of methanol content in technological lines of low-temperature gas separation plants was carried out using the Aspen HYSYS simulator. The power of electromagnetic radiation was determined using the Pipe3 computer program developed by the author. The results of industrial implementation and the economic efficiency of the developed technology were analyzed using industrial data processing and analysis methods.
Findings. The technology for using methanol in low-temperature gas preparation processes using microwave radiation energy has been developed. The choice of a site for installing a magnetron between the choke device and the second-stage separator has been substantiated. A new design of a removable insert with a magnetron has been proposed. A distinctive feature of the development is the creation of a resonant zone between the choke and the diaphragm. The installation of a microwave emitter in the technological scheme of a low-temperature separation installation has been proposed. A method for selecting the magnetron power depending on the concentration of hydrates in the flow has been determined. Technical limitations of the technology for pressure, pipeline diameter and phase movement regime have been established. The results of testing a new technology for using methanol in the conditions of the Zakhidny Radchenko gasification plant are presented.
The originality. New approximate dependences of specific methanol and electricity consumption on daily gas consumption have been established for the use of microwave radiation technology in low-temperature gas preparation processes in a certain range of gas consumption.
Practical implementation. The proposed technology for methanol application in low-temperature gas treatment processes using ultra-high frequency radiation energy ensures hydrate-free operation of integrated gas treatment units, reduces the consumption of expensive and toxic methanol, and lessens the environmental impact.
Keywords: hydrate formation, methanol, ultra-high frequency electromagnetic radiation, energy efficiency, gas treatment, low-temperature separation, natural gas, mathematical modeling.
References
1. Dmytrenko, V., & Podoliak, T. (2024). Research of methanol content in technological flows of facilities that process gas preparation by low-temperature separation method. Technology Audit and Production Reserves, 6(1 (80)), 46–53. https://doi.org/10.15587/2706-5448.2024.318926
2. Volovetskyi, V. B., Vytiaz, O. Yu., & Shchyrba, O. M. (2010). Poperedzhennia vidkladannia hidrativ ta zbyrannia ridyny pid chas produvannia sverdlovyny ta shleifu. Rozvidka ta rozrobka naftovykh i hazovykh rodovyshch, 1(34), 160–164. http://elar.nung.edu.ua/bitstream/123456789/4125/1/986p.pdf
3. Yang, H., Liu, X., Yue, J., & Tang, X. (2021). Analysis of factors affecting microwave heating of natural gas hydrate combined with numerical simulation method. Petroleum, 8(3), 391–402. https://doi.org/10.1016/j.petlm.2021.12.003
4. Bera, A., & Babadagli, T. (2017). Effect of native and injected nano-particles on the efficiency of heavy oil recovery by radio frequency electromagnetic heating. Journal of Petroleum Science and Engineering, 153, 244–256. https://doi.org/10.1016/j.petrol.2017.03.051
5. Bondarenko, V. I., Sai, K. S., Hanushevych, K. A., & Ovchynnikov, M. P. (2015). Rozrobka matematychnoi modeli intensyfikatsii protsesu hidratoutvorennia za rezultatamy eksperymentalnykh doslidzhen. Rozrobka rodovyshch, 9(1), 259–266. https://rr.nmu.org.ua/pdf/2015/20150906-34.pdf
6. Rojey, A., & Larue, J. (1988). Integrated process for the treatment of a methane-containing wet gas in order to remove water therefrom (U.S. Patent No. 4,775,395). U.S. Patent and Trademark Office. https://patents.google.com/patent/US4775395
7. Dmytrenko, V. I., & Podoliak, T. M. (2024, 12–13 hrudnia). Tekhnolohii vykorystannia metanolu na ustanovkakh NTS. V Akademichna y universytetska nauka: rezultaty ta perspektyvy: Zbirnyk naukovykh prats XVII-oi Mizhnarodnoi naukovo-tekhnichnoi konferentsii (s. 319–322). Natsionalnyi universytet «Poltavska politekhnika imeni Yuriia Kondratiuka». https://reposit.nupp.edu.ua/files/original/178/18902/8bcff7b30b76c8d3d57f0e2fa0133eb3065979e7.pdf
8. Satenov, K. G., Tkenbayev, S. M., Tashenov, Z. A., & Akhmetov, Z. E. (2024). Processes of methanol regeneration from water-methanol solutions in the oil and gas industry. Kazakhstan Journal for Oil & Gas Industry, 6(1), 99–109. https://doi.org/10.54859/kjogi108691
9. Nielsen, R. B., & Bucklin, R. W. (1983). Why not use methanol for hydrate control? Hydrocarbon Processing, 62(4), 71–78. https://www.osti.gov/biblio/5382028
10. Mukhsaf, M. H., Li, W., & Jani, G. H. (2025). Optimizing methanol injection quantity for gas hydrate inhibition using machine learning models. Applied Sciences, 15(6), 3229. https://doi.org/10.3390/app15063229
11. Khan, S. H., Misra, A. K., Majumder, C. B., & Arora, A. (2020). Hydrate dissociation using microwaves, radio frequency, ultrasonic radiation, and plasma techniques. ChemBioEng Reviews, 7(4), 130–146. https://doi.org/10.1002/cben.202000004.
12. Tang, L. G., Xiao, R., Huang, C., Feng, Z. P., & Fan, S. S. (2005). Experimental Investigation of Production Behavior of Gas Hydrate under Thermal Stimulation in Unconsolidated Sediment. Energy & Fuels, 19(6), 2402–2407. https://doi.org/10.1021/ef050223g
13. Wang, B., Fan, Z., Wang, P., Liu, Y., Zhao, J., & Song, Y. (2020). Numerical analysis of microwave stimulation for enhancing energy recovery from depressurized methane hydrate sediments. Applied Energy, 262, Article 114559. https://doi.org/10.1016/j.apenergy.2020.114559.
14. Wang, Y., Li, X. S., Guan, P., Fan, S. S., & Chen, J. L. (2024). Study on microwave heating energy supplement technology for gas hydrate reservoir. Energy, 286, Article 129624. https://doi.org/10.1016/j.energy.2023.129624
15. Dreus, A. Y., Horbiei, M. S., Dmytrenko, V. I., & Kozii, S. V. (2022). Numerical study of microwave impact on gas hydrate plugs in a pipeline. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, (4), 28–34. https://doi.org/10.33271/nvngu/2022-4/028.
16. Wang, S., Zhu, Y., Bondarenko, V., Dreus, A., Liang, J., & Liu, B. (2021). Design and numerical simulation of a microwave antenna with coaxial slots for preventing secondary formation of gas hydrate. E3S Web of Conferences, 230, 1008. https://doi.org/10.1051/e3sconf/202123001008
17. Chong, Z. R., Yang, S. H. B., Babu, P., Linga, P., & Li, X. S. (2016). Review of natural gas hydrates as an energy resource: Prospects and challenges. Applied Energy, 162, 1633–1652. https://doi.org/10.1016/j.apenergy.2014.12.061
18. Davletshina, M. R., Stolpovsky, M. V., Chiglintseva, A. S., & Gimaltdinov, I. K. (2020). Features of decomposition of gas hydrate when exposed to microwave radiation. IOP Conference Series: Materials Science and Engineering, 919(6), 62071. https://doi.org/10.1088/1757-899x/919/6/062071
19. Microwave antenna assembly and methods (2018). (Patent WO2018191743A1)
20. Kondrat, O. R., & Hutak, A. D. (2015). Enerhoefektyvna modyfikatsiia ustanovky nyzkotemperaturnoi separatsii hazu. Naftohazova haluz Ukrainy, (5), 26–30. http://elar.nung.edu.ua/bitstream/123456789/317/3/5186p.pdf
21. Podoliak, T. M., & Dmytrenko, V. I. (2026, 18 bereznia). Udoskonalennia konstruktsii prystroiu dlia mikrokhvylovoho zapobihannia hidratoutvorennia u promyslovykh hazoprovodakh. V Tezy KhVI Vseukrainskoi konferentsii molodykh vchenykh «Molodi vcheni 2026 – vid teorii do praktyky» (s. 516–520). NTU «Dniprovska politekhnika». https://drive.google.com/file/d/17uytircluOGv3xILxEk6WOu9QGh0ePMN/view
date of first submission of the article to the publication – 01/17/2026
date of acceptance of the article for publication after review – 02/21/2026
date of publication – 03/302026