№64-04
Estimation of the efficiency of destroying hard rocks by composites sintered in the diamond-carbonate system
A. Isonkin1, A. Osipov1, А. Matviichuk1
1V. Bakul Institute for superhard materials of NAS of Ukraine,Kyiv
Coll.res.pap.nat.min.univ. 2021, 64:43-54
https://doi.org/10.33271/crpnmu/64.043
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ABSTRACT
The purpose of this work is to substantiate the possibility of using a new composite sintered in the "diamond-carbonate" system for equippingdiamond drilling tools with high wear resistance and efficiency of rock destruction.
The research technique consisted in establishing the influence of the wear resistance of the cutting edge of the samplesof a superhard composite diamond-containing material on the efficiency of rock destruction, assessed by the granulometric composition of its sludge.
Research results. The two-phase superhard composite materials diamond – CaMg(CO3)2 and diamond – SrCO3 were obtained as a result of sintering by the method of impregnation of diamond micropowder with carbonate melts under conditions of a high pressure of 8.0 GPa and a temperature of 2100 °C. Wear resistance of the investigated composite sampleswas determined by based on the results of turning the core of granite from the Korostyshevskoye deposit of the X category of drilling. Determination of the size and shape of particles of granite fragments of the Korostyshevskoye deposit, taken during its destruction was carried out by laser diffraction and digital image analysis using a Microtrac Sync analyzer.The relationship between the degree of its wear of the cutting edge of composite samplesand the energy consumption of rock destruction, the size distribution of particles in the cuttings sample and their specific surface was established after analyzing the results of the study of wear resistance and the nature of their wear. Plates of the diamond–CaMg(CO3)2 composite, which have a higher wear resistance compared to other composites, are characterized by an increase in the proportion of large particles in the cuttings sample and a decrease in the value of their specific surface, which indicates a more rational use of energy, which goes to a greater extent for destruction rock and to a lesser extent for friction and wear.
Practical value. The research results allow us to make a conclusion about the advisability of equipping a drilling rock cutting tool with samplesof a diamond–CaMg(CO3)2 composite in order to increase its wear resistance and the efficiency of rock destruction.
Keywords: diamond, dolomite, strontium carbonate, high pressure, destruction of rocks, wear, wear resistance.
References:
1. Clark, I. E, & Bex, P. A. (1999). The use of PDC for petroleum and mining drilling. Industrial diamond review, (1), 43–49.
2. Skott,D. E. (2006).The history and impact of synthetic diamond cutters and diamond enhanced inserts on the oil and gas industry. Industrial diamond review, (1), 48–55.
3. Rebinder, P.A. (1971). Issledovanie protsessov obrazovaniya dispersnykh struktur. Navuka i tekhnika.
4. Rzhevskiy, V.V., & Novik, G.Ya. (1978). Osnovy fiziki gornykh porod. Nedra.
5. Khodakov, G.S. (1972). Fizika izmel'cheniya. Nauka.
6. Spivak, A.I. (1967). Mekhanika gornykh porod. Nedra.
7. Pristash, V.V., & Chirkov, S.E. (2000). Energoemkost' razrusheniya gornykh porod pri razlichnykh vidakh mekhanicheskikh vozdeystviy. Gorn. inform.-analit. byul. Gornaya kn.,(10), 85-87.
8. Kanyanta V., Dormer A., Murphy N., Ivankovic A. (2014). Impact fatigue fracture of polycrystalline diamond compact (PDC) cutters and the effect of microstructure.Іnternational Journal of Refractory Metals and Hard Materials,(46),145–151.
https://doi.org/10.1016/j.ijrmhm.2014.06.003
9. Westraadt, J. E., Sigalas, I., & Neethling, J. H. (2015). Characterisation of thermally degraded polycrystalline diamond. International Journal of Refractory Metals and Hard Materials, 48, 286–292.
https://doi.org/10.1016/j.ijrmhm.2014.08.008
10. Qian, J., McMurray, C. E., Mukhopadhyay, D. K., Wiggins, J. K., Vail, M. A., & Bertagnolli, K. E. (2012). Polycrystalline diamond cutters sintered with magnesium carbonate in cubic anvil press. International Journal of Refractory Metals and Hard Materials, 31, 71–75.
https://doi.org/10.1016/j.ijrmhm.2011.09.008
11. Qian, J., McMurray, E., & Mukhopadhyay, D. (2013). Polycrystalline diamond compact including a carbonate-catalyzed polycrystalline diamond table and applications therefor(Pat. 2013/0043078 A1 USA, IC B24D 3/06)
12. Osipov, A. S., Klimczyk, P., Cygan, S., Melniychuk, Y. A., Petrusha, I. A., Jaworska, L., & Bykov, A. I. (2017). Diamond-CaCO 3 and diamond-Li 2 CO 3 materials sintered using the HPHT method. Journal of the European Ceramic Society, 37(7), 2553–2558.
https://doi.org/10.1016/j.jeurceramsoc.2017.02.028
13. Bao Y., Garan A., France M.D., Belnap J.D.(2014) Pat. 2014/0130418 A1 USA, IC E21B 10/567. Method of making carbonate PCD and sintering carbonate PCD on carbide substrate.
14. Akaishi, M., Kanda, H., & Yamaoka, S. (1990). Synthesis of diamond from graphite-carbonate system under very high temperature and pressure. Journal of Crystal Growth, 104(2), 578–581.
https://doi.org/10.1016/0022-0248(90)90159-I
15. Sato, K., Akaishi, M., & Yamaoka, S. (1999). Spontaneous nucleation of diamond in the system MgCO3–CaCO3–C at 7.7 GPa. Diamond and Related Materials, 8(10), 1900–1905.
https://doi.org/10.1016/S0925-9635(99)00157-0
16. Greg, S., & Sing. K. (1970) Adsorbtsiya, udel'naya poverkhnost', poristost'. Mir.
17. Izmerenie udel'noy poverkhnosti poroshkovykh materialov i postroenie izotermy ad-sorbtsii-desorbtsii na pribore «Akusorb» firmy «Kul'treniks» (1985), ISM AN USSR.