№70-07

Analysis of the influence of the с8н coal seam thickness of Dniprovska mine on the content of germanium

V. Ishkov1,2, Ye. Kozii1, O. Chernobuk3

1Dnipro University of Technology, Dnipro, Ukraine

2Institute of Geotechnical Mechanics named by N. Polіakovof National Academy of Sciences of Ukraine, Dnipro, Ukraine

3 Georgian Manganese, Tbilisi, Georgia

3Джорджиан Манганез, Тбілісі, Грузія

Coll.res.pap.nat.min.univ. 2022, 70:76-90

https://doi.org/10.33271/crpnmu/70.076

Full text (PDF)

ABSTRACT

Purpose. The factual basis of the work was the results of 370 analyzes of germanium and other impurity elements (they are also called "small elements"), measurements of formation thickness, ash content and sulfur content of coal performed in the central certified laboratories of production geological exploration organizations of Ukraine from the material of formation samples obtained by production and research enterprises and organizations. To bring the samples to the same scale, the raw data were normalized.To investigate and analyze the influence of the thickness of the coal seam с8н of the Dniprovska mine on the content of germanium and to develop an objective (natural) typification of the areas of the coal seam of different thickness according to the concentrations of this element.

Methodology. To achieve the goal, the work uses laboratory and statistical methods of scientific research, taking into account and interpreting the obtained results in geological concepts.In the course of the research, the clustering of seam sections of different thickness according to Ge content was carried out using the weighted centroid median method, which was implemented in the most popular professional statistical software platforms "STATISTICA" and "SPSS", and the analysis of the clustering results was performed.

Findigs. The implementation of the approach outlined in the article makes it possible to propose a natural typification of areas based on the thickness of the coal seam according to the germanium content. The analysis of the obtained modeling results indicates the manifestation of the so-called "Zilbermints law" –an empirical regularity of the enrichment of some elements (primarily germanium) in the near-contact zones of coal seams. The thickness of such layers usually does not exceed 0.2-0.3 m.

Scientific novelty. It consists in establishing the numerical characteristics of the differential influence of the thickness of the coal seam с8н of the Dniprovska mine on the content of Ge and the development of a natural typification of areas with different thickness of the с8н seam of the Dniprovska mine according to the concentration of this element.

Practical significance. It consists in the fact that a methodical approach and an algorithm of actions are proposed for the division of coal seams into natural, close in Ge content and genetically related areas, which provides the possibility of the most effective planning of organizational and technological measures and the implementation of their most likely geological and economic assessment, which is aimed at extraction of Ge from coal.

Keywords: germanium, coal seam, regression analysis, cluster analysis, distribution histogram, normalized content.

References

1. Naumov, A.V. (2007). Svitovyi rynok hermaniiu ta yoho perspektyvy. Izv. vuzov. Tsv. Metallurgiya, 4. 32-40.

2. Naumov, A. V. (2007). World market of germanium and its prospects. Russian Journal of Non-Ferrous Metals, 48(4), 265–272.
https://doi.org/10.3103/S1067821207040049

3. Ishkov, V.V., Kozii, Ye.S., & Klymenko, A.H. (2021). Osoblyvosti rozpodilu hermaniiu u vuhilnomu plasti c1 shakhty «Dniprovska». Mizhnarodna naukovo-tekhnichna konferentsiia «Problemy rozvytku hirnycho-promyslovykh raioniv», 42-50.

4. Ishkov, V.V., Kozii, Ye.S., & Slyvnyi, S.O. (2021). Pro rozpodil hermaniiu u vuhilnomu plasti s8v polia shakhty «Zakhidno-Donbaska». Mizhnarodna konferentsiia molodykh vchenykh «Heotekhnichni problemy rozrobky rodovyshch», 27-32.

5. Ishkov, V.V., Kozii, Ye.S., & Chernobuk, O.I. (2022) Zviazok hermaniiu iz zolnistiu u vuhilnomu plasti s10v shakhty «Dniprovska». XMizhnarodna naukovo-praktychna konferentsiia «Tekhnolohii i protsesy v hirnytstvi ta budivnytstvi», 25-33.

6. Goldshmidt, V. M. (1930). "Ueber das Vorkommen des Germaniums in Steinkohlen und Steinkohlenprodukten". Nachrichten von der Gesellschaft der Wissenschaften zu Göttingen, Mathematisch-Physikalische Klasse, 141-167.

7. Zilbermints, V. A., Rusanov, A. K, & Kostrykin, V. M. (1936). K voprosu o rasprostranenii germaniya v iskopaemykh uglyakh. Akademiku V.I. Vernadskomu k pyatidesyatiletiyu nauchnoy deyatelnosti, 1, 169-190.

8. Pavlov, A.V. (1966). Veshchestvennyy sostav zoly ugley nekotorykh rayonov Zapadnogo Shpitsbergena. Uch. zap. NIIGA. Regionaln. geol, 8, 128-136.

9. GOST 9815-75. Ugli burye, kamennye, antratsit i goryuchie slantsy. Metod otbora plastovykh prob. (1975). Izd-vo standartov.

10. GOST 10175-75. Ugli burye, kamennye, antratsity, argillity i alevrolity. Metody opredeleniya soderzhaniya germaniya. (1975). Izd-vo standartov.

11. GOST 10478-93. Toplivo tverdoe. Metody opredeleniya myshyaka. (1993). Izd-vo standartov.

12. GOST 28974-91. Ugli burye, kamennye i antratsity. Metody opredeleniya berilliya, bora, margantsa, bariya, khrom, nikelya, kobalta, svintsa, galliya, vanadiya, medi, tsinka, molibdena, ittriya i lantana. (1991). Izd-vo standartov.

13. Ishkov, V.V., & Koziy, E.S. (2014). O klassifikatsii ugolnykh plastov po soderzhaniyu toksichnykh elementov s pomoshchyu klasternogo analiza.  Zbirnyk naukovykh prats' NHU, 45, 209-221.

14. Kozii, Ye.S. (2017). Osoblyvosti rozpodilu toksychnykh i potentsiino toksychnykh elementiv u vuhilli plasta s10v shakhty «Stashkova» Pavlohradsko-Petropavlivskoho heoloho-promyslovoho raionu. Zbirnyk naukovykh prats «Heotekhnichna mekhanika», 132, 157-172.

15. Ishkov, V.V., & Kozii, Ye.S. (2017). Pro rozpodil toksychnykh i potentsiino toksychnykh elementiv u vuhilli plasta s10v shakhty «Dniprovska» Pavlohradsko-Petropavlivskoho heoloho-promyslovoho raionu Donbasu. Zbirnyk naukovykh prats «Heotekhnichna mekhanika», 133, 213-227.

16. Kozii, Ye.S. (2018). Mysh’iak, berylii, ftor i rtut u vuhilli plasta s8v shakhty "Dniprovska" Pavlohradsko-Petropavlivskoho heoloho-promyslovoho raionu. Visn. Dniprop. un-tu. Heol., heohraf, 26 (1), 113-120.
https://doi.org/10.15421/111812

17. Ishkov, V.V., Kozii, Ye.S., & Tsyba, A.S. (2021). Osoblyvosti rozpodilu deiakykh toksychnykh ta potentsiino toksychnykh elementiv u vertykalnomu rozrizi vuhilnoho plasta i «Zakon Zilbermintsia». Materialy konferentsii «Tyzhden studentskoi nauky 2021», 238-240.

18. Ishkov, V.V. Kozii, Ye.S., Tsyba, A.S., & Ponomarenko, O.V. (2021). Osoblyvosti rozpodilu deiakykh toksychnykh ta potentsiino toksychnykh elementiv u vertykalnomu rozrizi vuhilnykh plastiv Donbasu. Vseukrainska naukovo-praktychna konferentsiia «Aktualni problemy naukovo-promyslovoho kompleksu rehioniv», 80-82.

19. Ishkov, V., & Koziy, E. (2017). Distribution of toxic and potentially toxic elements in the coal of the layer s7nof the “Pavlogradskaya” mine of Pavlogradsko-Petropavlovskiy geological and industrial district. Visnyk of Taras Shevchenko National University of Kyiv. Geology, 79(4), 59–66.
https://doi.org/10.17721/1728-2713.79.09

20. Ishkov, V.V. (1999). Problemy heokhimii «malykh» i toksychnykh elementiv u vuhilli Ukrainy. Nauk. visnyk NHA Ukrainy, 1, 128-132

21. Yudovich, Ya.E. (1978). Geokhimiya iskopaemykh ugley. Nauka.

22. Yudovich, Ya.E. (1965). Raspredelenie elementov v vertikalnom profile ugolnykh plastov. Nedra, 7, 134-142.

23. Yudovich, Ya.E., & Ketris, M.P. (2005). Selen v uglyakh. Geoprint.

24. Kozii, Ye.S., & Ishkov, V.V. (2017). Klasyfikatsiia vuhillia osnovnykh robochykh plastiv Pavlohradsko-Petropavlivskoho heoloho-promyslovoho raionu po vmistu toksychnykh i potentsiino toksychnykh elementiv. Zb. nauk. pr. «Heotekhnichna mekhanika», 136, 74-86.

25. Ishkov, V.V., Serdyuk, E.A., & Slipenkiy, E.V. (2003). Osobennosti primeneniya metodov klasternogo analiza dlya klassifikatsii ugolnykh plastov po soderzhaniyu toksichnykh i potentsialno toksichnykh elementov (na primere Krasnoarmeyskogo geologo-promyshlennogo rayona). Sb. nauch. tr. NGU, 1 (19), 5-16.

26. Ishkov, V.V., Chernobuk, O.I., Berezniak, O., & Diachkov, P.A. (2022). Doslidzhennia metodiv klasteryzatsii dilianok riznoi potuzhnosti vuhilnoho plasta z metoiu stvorennia yikh pryrodnoi typizatsii za vmistom hermaniiu (na prykladi plasta s8n shakhty «Dniprovska», Ukraina). Problems of the development of modern science. Proceedings of the ХХXIV International Scientific and Practical Conference, 86-95.
https://doi.org/10.46299/ISG.2022.1.34

27. Kozar, M.A., Ishkov, V.V., Kozii, Ye.S., & Strielnyk, Yu.V. (2021). Toksychni elementy mineralnoi ta orhanichnoi skladovoi vuhillia nyzhnoho karbonu Zakhidnoho Donbasu. Heolohichna nauka v nezalezhnii Ukraini: Zbirnyk tez naukovoi konferentsii In-tu heokhimii, mineralohii ta rudoutvorennia im. M.P. Semenenka NAN Ukrainy, 55-58.

28. Yerofieiev, A., Ishkov, V., Kozii, Y., & Bartashevskiy, S. (2021). Research of clusterization methods of oil deposits in the Dnipro-Donetsk depression with the purpose of creating their classification by metal content (on the vanadium example). Scientific Papers of DonNTU Series: “The Mining and Geology” 12(25–26), 83–93.
https://doi.org/10.31474/2073-9575-2021-1(25)-2(26)-83-93

29. Kozii, Ye.S. (2021). Toxic elements in the с1 coal seam of the Blahodatna mine of Pavlohrad-Petropavlivka geological and industrial area of Donbas.Collection of scientific works "Geotechnical Mechanics", 158, 103-116.
https://doi.org/10.15407/geotm2021.158.103

30. Kozii,Ye.S. (2021). Arsenic, mercury, fluorine and beryllium in the с1 coal seam of the Blahodatna mine of Pavlohrad-Petropavlivka geological and industrial area of western Donbas. Collection of scientific works "Geotechnical Mechanics",159, 58-68.
https://doi.org/10.15407/geotm2021.159.058

31. Kozii,Ye. (2020). Coal height of coal seam k5 of "Kapitalna" mine.Proceedings of the "Widening Our Horizons": International Forum for Students and Young Researchers,399-401.

32. Yerofieiev, A.М., Ishkov, V.V., Kozii, Ye.S., & Bartashevskiy, S.Ye. (2021). Geochemical features of nickel in the oils of the Dnipro-Donetsk basin. Collection of scientific works "Geotechnical Mechanics", 160,17-30.
https://doi.org/10.15407/geotm2021.160.017

Ishkov, V., & Kozii, Y. (2020). Distribution of mercury in coal seam c7nof Pavlohradska mine field. Scientific Papers of DonNTU Series: “The Mining and Geology” 12(23–24), 26–33.
https://doi.org/10.31474/2073-9575-2020-3(23)-4(24)-26-33

34. Kozii, Ye. (2021). Chromium in the coal seams of the Chervonoarmiiskyi geological and industrial area of Donbas. Proceedings of the "Widening Our Horizons": International Forumfor Students and Young Researchers,453-455.

35. Ishkov, V. V., & Kozii, Y. S. (2021). Distribution of Arsene and Mercury in the Coal Seam k5 of the Kapitalna Mine, Donbas. Mineralogical Journal, 43(4), 73–86
https://doi.org/10.15407/mineraljournal.43.04.073

36. Ishkov, V. V., & Kozii, Ye. S. (2020). Some features of beryllium distribution in the k5 coal seam of the “Kapitalna” mine of the krasnoarmiiskyi geological and industrial district of Donbas. Odesa National University Herald. Geography and Geology, 25(1(36)), 214–227.
https://doi.org/10.18524/2303-9914.2020.1(36).205180

37. Ishkov, V. V., & Kozii, Y. S. (2021). Peculiarities of lead distribution in coal seams of Donetsk-Makiivka geological and industrial area of Donbas. Tectonics and Stratigraphy, 47, 77–90.
https://doi.org/10.30836/igs.0375-7773.2020.216155

38. Mametova, L.F., Mirek, A., & Kozii, Ye.S.(2020). Pyritization of the Middle Carboniferous Sandstones of the Donbas. Mineral. Journ. (Ukraine), 42(2), 14-19.
https://doi.org/10.15407/mineraljournal.42.02.014

39. Ishkov, V.V., & Koziy, E.S. (2021). Nakoplenie Co i Mn na primere plasta s5 Zapadnogo Donbassa kak rezultat ikh migratsii iz kor vyvetrivaniya Ukrainskogo kristallicheskogo shchita. Materialy Mezhdunarodnogo soveshchaniya po geologii rossypey i mestorozhdeniy kor vyvetrivaniya «Rossypi i mestorozhdeniya kor vyvetrivaniya XXI veka: zadachi, problemy, resheniya», 160-162.

40. Kozar, M.А., Ishkov, V.V., Kozii,Ye.S., & Pashchenko, P.S. (2020). New data about the distribution of nickel, lead and chromium in the coal seams of the Donetsk-Makiivka geological and industrial district of the Donbas. Journ. Geol. Geograph. Geoecology, 29(4),722-730.
https://doi.org/10.15421/112065

41. Ishkov, V. V., & Kozii, Y. S. (2019). Analysis of the distribution of chrome and mercury in the main coals of the red army geological and industrial area. Tectonics and Stratigraphy, 46, 96–104.
https://doi.org/10.30836/igs.0375-7773.2019.208881

42. Nesterovskyi, V., Ishkov, V., & Kozii, Y. (2020). Toxic and potentially toxic elements in the coal of the seam s8nof the “Blagodatna” mine of Pavlohrad-Petropavlivka geological and industrial area. Visnyk of Taras Shevchenko National University of Kyiv. Geology, 1 (88), 17–24.
http://doi.org/10.17721/1728-2713.88.03

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